Origins of high catalyst loading in copper(i)-catalysed Ullmann–Goldberg C–N coupling reactions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02859h Click here for additional data file.

Copper(i)-catalyzed sulfonylative Suzuki–Miyaura cross-coupling† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc05483h Click here for additional data file.

The total synthesis of K-252c (staurosporinone) via a sequential C–H functionalisation strategy† †Electronic supplementary information (ESI) available: 1H and 13C NMR spectra, and crystallographic data. CCDC 1431476. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc04399a Click here for additional data file. Click here for additional data file.

A synthesis of the bioactive indolocarbazole alkaloid K-252c (staurosporinone) via a sequential C–H functionalisation strategy is reported. The route exploits direct functionalisation reactions around a simple arene core and comprises of two highly-selective copper-catalysed C–H arylations, a coppercatalysed C–H amination and a palladium-catalysed C–H carbonylation, which build up the structura...

Pyridine sulfinates as general nucleophilic coupling partners in palladium-catalyzed cross-coupling reactions with aryl halides† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc00675f Click here for additional data file.

Enantioselective propargylic [1,3]-rearrangements: copper-catalyzed O-to-N migrations toward C–N bond formation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc01042g Click here for additional data file. Click here for additional data file.

A rational pre-catalyst design for bis-phosphine mono-oxide palladium catalyzed reactions† †Electronic supplementary information (ESI) available: Detailed experimental procedures and characterization data for all new compounds. CCDC 1512973–1512975. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05472b Click here for additional data file. Click here for additional data file.